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LYU Yining, GONG Jing, WANG Jiaqi, QIN Wei, SHI Bohui. Research progress on formation model of gas hydrate in water-in-oil emulsion[J]. Oil & Gas Storage and Transportation, 2017, 36(6): 674-682. DOI: 10.6047/j.issn.1000-8241.2017.06.010
Citation: LYU Yining, GONG Jing, WANG Jiaqi, QIN Wei, SHI Bohui. Research progress on formation model of gas hydrate in water-in-oil emulsion[J]. Oil & Gas Storage and Transportation, 2017, 36(6): 674-682. DOI: 10.6047/j.issn.1000-8241.2017.06.010
shu

Research progress on formation model of gas hydrate in water-in-oil emulsion

  • 1.

    Beijing Key Laboratory of Urban Oil and Gas Distribution Technology, China University of Petroleum (Beijing) /National Engineering Laboratory for Pipeline Safety/MOE Key Laboratory of Petroleum Engineering

  • 2.

    PetroChina Oil and Gas Pipeline Control Center

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  • Received Date: February 25, 2017
  • Revised Date: May 13, 2017
  • Available Online: August 20, 2023
  • Published Date: April 16, 2017
    Graphical Abstract
    • Abstract
  • The transportation of deepwater oil and gas resources will be threatened seriously once pipelines are plugged by hydrate. Therefore, it is essential to predict quantitatively the formation of hydrate in different working conditions. At present, however, the formation kinetics mechanisms of gas hydrate are not clear. In this paper, the domestic and foreign research progress on formation kinetics of hydrate in water-in-oil systems was illustrated systematically, the kinetics model used for nucleation and growth of gas hydrate in the oil-gas-water multiphase systems with oil as the dominant phase was mainly introduced. Then, the advantages and disadvantages of main models were analyzed. Finally, based on the status of researches on formation kinetics of gas hydrate in water-in-oil emulsion systems, it was recommended to study the formation of hydrate in multiphase systems with the coupling mechanism of mass transfer and intrinsic reaction as the beginning point. And then combined with the test studies of different scales, a more applicable model for the formation of hydrate will be established by taking into consideration the physical process, mass transfer and heat transfer restriction in multiphase systems, so as to provide the assurance for the flow safety of pipelines.
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    • References (43)
  • [1]
    SLOAN E D, KOH C A. Clathrate hydrates of natural gases[M]. Florida: CRC Press, 2007: 1-176.
    [2]
    RIBEIRO C P, LAGE P L C. Modelling of hydrate formation kinetics: State-of-the-art and future directions[J]. Chemical Engineering Science, 2008, 63(8): 2007-2034. doi: 10.1016/j.ces.2008.01.014
    [3]
    TURNER D J, MILLER K T, SLOAN E D. Methane hydrate formation and an inward growing shell model in water-in-oil dispersions[J]. Chemical Engineering Science, 2009, 64(18): 3996-4004. doi: 10.1016/j.ces.2009.05.051
    [4]
    SHI B H, GONG J, SUN C Y, et al. An inward and outward natural gas hydrates growth shell model considering intrinsic kinetics, mass and heat transfer[J]. Chemical Engineering Journal, 2011, 171(3): 1308-1316. doi: 10.1016/j.cej.2011.05.029
    [5]
    GONG J, SHI B H, ZHAO J K. Natural gas hydrate shell model in gas-slurry pipeline flow[J]. Journal of Natural Gas Chemistry, 2010, 19(3): 261-266. doi: 10.1016/S1003-9953(09)60062-1
    [6]
    LYU X F, SHI B H, WANG Y, et al. Study on gas hydrate formation and hydrate slurry flow in a multiphase transportation system[J]. Energy & Fuels, 2013, 27(12): 7294-7302.
    [7]
    阮超宇, 史博会, 宋尚飞, 等. 天然气凝析液管道水合物堵管风险概率研究[J]. 石油科学通报, 2016, 1(2): 257-269. https://www.cnki.com.cn/Article/CJFDTOTAL-SYKE201602008.htm

    RUAN C Y, SHI B H, SONG S F, et al. Study of hydrate plugging risk in gas-condensate pipelines[J]. Petroleum Science Bulletin, 2016, 1(2): 257-269. https://www.cnki.com.cn/Article/CJFDTOTAL-SYKE201602008.htm
    [8]
    SHI B H, LIU Y, DING L, et al. Simulation of gas-hydrate slurry stratified flow with inward and outward hydrate growth model[C]. Calgary: The 11th International Pipeline Conference, 2016: V002T08A004.
    [9]
    MU L, LI S, MA Q L, et al. Experimental and modeling investigation of kinetics of methane gas hydrate formation in water-in-oil emulsion[J]. Fluid Phase Equilibria, 2014, 362: 28-34. doi: 10.1016/j.fluid.2013.08.028
    [10]
    CHEN G J, GUO T M. A new approach to gas hydrate modelling[J]. Chemical Engineering Journal, 1998, 71(2): 145-151. doi: 10.1016/S1385-8947(98)00126-0
    [11]
    DALMAZZONE D, HAMED N, DALMAZZONE C. DSC measurements and modelling of the kinetics of methane hydrate formation in water-in-oil emulsion[J]. Chemical Engineering Science, 2009, 64(9): 2020-2026. doi: 10.1016/j.ces.2009.01.028
    [12]
    LI X, CHEN C, CHEN Y, et al. Kinetics of methane clathrate hydrate formation in water-in-oil emulsion[J]. Energy & Fuels, 2015, 29(4): 2277-2288.
    [13]
    ZERPA L E. A practical model to predict gas hydrate formation, dissociation and transportability in oil and gas flowlines[D]. Golden: Colorado School of Mines, 2013: 84-97, 119-134.
    [14]
    AMAN Z M, BROWN E P, SLOAN E D, et al. Interfacial mechanisms governing cyclopentane clathrate hydrate adhesion/ cohesion[J]. Physical Chemistry Chemical Physics, 2011, 13(44): 19796-19806. doi: 10.1039/c1cp21907c
    [15]
    VYSNIAUSKAS A, BISHNOI P R. A kinetic study of methane hydrate formation[J]. Chemical Engineering Science, 1983, 38(7): 1061-1072. doi: 10.1016/0009-2509(83)80027-X
    [16]
    TURNER D, BOXALL J, YANG S, et al. Development of a hydrate kinetic model and its incorporation into the OLGA2000 ® transient multiphase flow simulator[C]. Trondheim: Proceedings of the 5th International Conference on Gas Hydrates, 2005: 4018.
    [17]
    HINZE J O. Fundamentals of the hydrodynamic mechanism of splitting in dispersion processes[J]. AIChE Journal, 1955, 1(3): 289-295. doi: 10.1002/aic.690010303
    [18]
    TURNER D J, MILLER K T, SLOAN E D. Direct conversion of water droplets to methane hydrate in crude oil[J]. Chemical Engineering Science, 2009, 64(23): 5066-5072. doi: 10.1016/j.ces.2009.08.013
    [19]
    BOXALL J. Hydrate plug formation from < 50% water content water-in-oil emulsions[D]. Golden: Colorado School of Mines, 2009: 65-95, 115-148.
    [20]
    DAVIES S R. The role of transport resistances in the formation and remediation of hydrate plugs[D]. Golden: Colorado School of Mines, 2009: 39-56, 146-190.
    [21]
    MA Q L, CHEN G J, WANG X L, et al. Kinetics of gas hydrate formation from pyrolysis gas in water-in-oil emulsion system[C]. Edinburgh: Proceedings of the 7th International Conference on Gas Hydrates, 2011: 2011.
    [22]
    KASHCHIEV D, FIROOZABADI A. Nucleation of gas hydrates[J]. Journal of crystal growth, 2002, 243(3): 476-489.
    [23]
    KASHCHIEV D, FIROOZABADI A. Induction time in crystallization of gas hydrates[J]. Journal of Crystal Growth, 2003, 250(3): 499-515.
    [24]
    TALATORI S, BARTH T. Rate of hydrate formation in crude oil/gas/water emulsions with different water cuts[J]. Journal of Petroleum Science and Engineering, 2011, 80(1): 32-40. doi: 10.1016/j.petrol.2011.10.010
    [25]
    KASHCHIEV D. Nucleation[M]. Oxford: ButterworthHeinemann, 2000: 373-390.
    [26]
    FIDEL-DUFOUR A, GRUY F, HERRI J M. Rheology of methane hydrate slurries during their crystallization in a water in dodecane emulsion under flowing[J]. Chemical Engineering Science, 2006, 61(2): 505-515. doi: 10.1016/j.ces.2005.07.001
    [27]
    SONG X F, XIN F, YAN H C, et al. Intensification and kinetics of methane hydrate formation under heat removal by phase change of n-tetradecane[J]. AIChE Journal, 2015, 61(10): 3441-3450. doi: 10.1002/aic.14867
    [28]
    LI X G, LI Y, ZHANG L H, et al. Absorption-hydration hybrid method for ethylene recovery from refinery dry gas: Simulation and evaluation[J]. Chemical Engineering Research and Design, 2016, 109: 258-272. doi: 10.1016/j.cherd.2016.01.022
    [29]
    LI Y, LI X G, ZHOU W T, et al. Kinetics of ethylene hydrate formation in water-in-oil emulsion[J]. Journal of the Taiwan Institute of Chemical Engineers, 2017, 70: 79-87. doi: 10.1016/j.jtice.2016.10.048
    [30]
    GIRALDO C, MAINI B, BISHNOI R, et al. A simplified approach to modeling the rate of formation of gas hydrates formed from mixtures of gases[J]. Energy & Fuels, 2013, 27 (3): 1204-1211.
    [31]
    周文涛, 李优, 李鑫钢, 等. 油水乳液中水合物法分离甲烷/乙烯生成动力学[J]. 化工学报, 2016, 67(8): 3446-3451. https://www.cnki.com.cn/Article/CJFDTOTAL-HGSZ201608037.htm

    ZHOU W T, LI Y, LI X G, et al. Kinetics of hydrate formation in water-oil emulsion for separation of methane and ethylene[J]. CIESC Journal, 2016, 67(8): 3446-3451. https://www.cnki.com.cn/Article/CJFDTOTAL-HGSZ201608037.htm
    [32]
    LYU Y N, SUN C Y, LIU B, et al. A water droplet size distribution dependent modeling of hydrate formation in water/ oil emulsion[J]. AIChE Journal, 2016, 63(3): 1010-1023.
    [33]
    ENGLEZOS P, KALOGERAKIS N, DHOLABHAI P, et al. Kinetics of formation of methane and ethane gas hydrates[J]. Chemical Engineering Science, 1987, 42(11): 2647-2658. doi: 10.1016/0009-2509(87)87015-X
    [34]
    DAVIES S R, SLOAN E D, SUM A K, et al. In situ studies of the mass transfer mechanism across a methane hydrate film using high-resolution confocal raman spectroscopy[J]. The Journal of Physical Chemistry, 2010, 114(2): 1173-1180.
    [35]
    LI S L, WANG Y F, SUN C Y, et al. Factors controlling hydrate film growth at water/oil interfaces[J]. Chemical Engineering Science, 2015, 135: 412-420. doi: 10.1016/j.ces.2015.01.057
    [36]
    SERVIO P, ENGLEZOS P. Morphology of methane and carbon dioxide hydrates formed from water droplets[J]. AIChE Journal, 2003, 49(1): 269-276. doi: 10.1002/aic.690490125
    [37]
    DAVIES S R, LACHANCE J W, SLOAN E D, et al. Highpressure differential scanning calorimetry measurements of the mass transfer resistance across a methane hydrate film as a function of time and subcooling[J]. Industrial & Engineering Chemistry Research, 2010, 49(23): 12319-12326.
    [38]
    SUN C Y, PENG B Z, DANDEKAR A, et al. Studies on hydrate film growth[J]. Annual Reports Section"C" (Physical Chemistry), 2010, 106: 77. doi: 10.1039/b811053k
    [39]
    LEBA H, CAMEIRAO A, HERRI JM, et al. Chord length distributions measurements during crystallization and agglomeration of gas hydrate in a water-in-oil emulsion: Simulation and experimentation[J]. Chemical Engineering Science, 2010, 65(3): 1185-1200. doi: 10.1016/j.ces.2009.09.074
    [40]
    GREAVES D, BOXALL J, MULLIGAN J, et al. Measuring the particle size of a known distribution using the focused beam reflectance measurement technique[J]. Chemical Engineering Science, 2008, 63(22): 5410-5419. doi: 10.1016/j.ces.2008.07.023
    [41]
    CHEN J, YAN K L, CHEN G J, et al. Insights into the formation mechanism of hydrate plugging in pipelines[J]. Chemical Engineering Science, 2015, 122: 284-290. doi: 10.1016/j.ces.2014.09.039
    [42]
    SUM A K, KOH C A, SLOAN E D. Developing a comprehensive understanding and model of hydrate in multiphase flow: from laboratory measurements to field applications[J]. Energy & Fuels, 2012, 26(7): 4046-4052.
    [43]
    DING L, SHI B H, LV X F, et al. Investigation of natural gas hydrate slurry flow properties and flow patterns using a high pressure flow loop[J]. Chemical Engineering Science, 2016, 146: 199-206. doi: 10.1016/j.ces.2016.02.040
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