盐沉积量对埕岛海域大气腐蚀性分级的影响
The influence of Salt Deposits on Classification of Marine Atmospheric Corrosivity at Chengdao Region
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摘要: 根据现场失重挂片试验, 采用ISO9223标准对埕岛海域大气腐蚀进行分级。海洋大气对碳钢的腐蚀大约比内陆大气腐蚀要高100倍, 海洋大气环境下室外的腐蚀比室内要高近10倍, 主要原因取决于金属表面盐沉积量。采用离子选择电极法测量现场试片表面盐沉积量, 室外试片的表面盐沉积量比室内的平均高40倍以上。在实验室内用腐蚀探测电池模拟研究盐沉积量对腐蚀性的影响, 在大气湿度超过临界相对湿度时, 少量盐沉积可使大气腐蚀性提高几个数量级, 并使临界相对湿度值从60%降低为40%。Abstract: According to in-situ weightlessness tests at Chengdao region, the atmospheric corrosivity was classified by ISO 9223 standard. The corrosion rates of carbon steel in marine atmosphere were more than 100 times the rates in land's atmosphere. The indoor corrosion under marine environment was about ten times lower than outdoor corrosion, because of difference of salt deposit. The salt deposits on corrosion coupons were measured by methods of iron-selection electrodes. The salt deposits on outdoor coupons were 40 times higher in average than on indoor coupons. The influences of salt deposits on corrosion of carbon steel were investigated in analogue environments by means of corrosion detective cells. The regression analysis showed that the atmospheric corrosivity had liner relationship with salt deposits in logarithm scales. Small amount of salt deposites make the corrosion of carbon steels increased in orders of magnitude, with critical relative humidity to move down from 60% to 40%.