陈振华, 陈洪源, 张腾, 闫茂成, 高博文. 不同土壤环境中X80钢剥离防腐层下的腐蚀行为对比分析[J]. 油气储运. DOI: 10.6047/j.issn.1000-8241.202503100096
引用本文: 陈振华, 陈洪源, 张腾, 闫茂成, 高博文. 不同土壤环境中X80钢剥离防腐层下的腐蚀行为对比分析[J]. 油气储运. DOI: 10.6047/j.issn.1000-8241.202503100096
CHEN Zhenhua, CHEN Hongyuan, ZHANG Teng, YAN Maocheng, GAO Bowen. Experimental study on pipeline corrosion under disbonded coating in different type of soil environments[J]. Oil & Gas Storage and Transportation. DOI: 10.6047/j.issn.1000-8241.202503100096
Citation: CHEN Zhenhua, CHEN Hongyuan, ZHANG Teng, YAN Maocheng, GAO Bowen. Experimental study on pipeline corrosion under disbonded coating in different type of soil environments[J]. Oil & Gas Storage and Transportation. DOI: 10.6047/j.issn.1000-8241.202503100096

不同土壤环境中X80钢剥离防腐层下的腐蚀行为对比分析

Experimental study on pipeline corrosion under disbonded coating in different type of soil environments

  • 摘要: 【目的】埋地钢质管道高绝缘性3PE防腐层剥离后会造成“阴极保护屏蔽”,所引起的局部环境下管道金属腐蚀一直是困扰油气管道行业的难点问题。为分析和评估防腐层剥离区内管道金属腐蚀发展规律,指导制定防护策略,结合防腐层剥离模拟实验装置,研究了X80钢不同土壤环境中剥离防腐层下管道电位分布特征和腐蚀行为。【方法】采用自制的防腐层剥离厚度可调的模拟实验装置,通过剥离区内不同位置的金属阴极保护电位测试,结合扫描电子显微镜、激光共聚焦显微镜表征,研究了滨海盐渍土、内地盐碱土、红黏土和草甸土等土壤溶液环境中,沿防腐层剥离延伸方向的管道金属阴极保护电位分布情况及剥离区内不同位置的局部微区腐蚀特征。【结果】管道金属的阴极保护电位会随剥离区深度发展而正移,有效的阴极保护主要集中在防腐层破损开口附近,随着深度延伸,阴极保护电位会快速衰减,直至剥离区深处管道接近自然腐蚀状态,即达到阴极保护屏蔽区;剥离区阴极保护电位分布和有效保护范围受剥离区液膜厚度和土壤水含盐量(土壤电阻率)影响,高盐含量、电阻率低的滨海盐渍土更有利于阴极保护电流穿透,且剥离区空间限制离子扩散和迁移过程,进而显著影响电流的分布及有效保护范围,【结论】对比管道在不同土壤中的腐蚀行为,阴极保护有效保护范围大小依次为滨海盐渍土﹥红黏土﹥内地盐碱土﹥草甸土。管道在滨海盐渍土和红黏土中局部腐蚀严重,而在内地盐碱土和草甸土中主要为均匀腐蚀,且剥离区管线钢腐蚀速率显著高于开放的防腐层破损点处。

     

    Abstract: The disbondment of highly insulating triple-layer polyethylene (3PE) coatings on buried steel pipelines can induce "cathodic protection (CP) shielding", and the resulting localized corrosion has long been a critical challenge in oil and gas pipeline industry. This study investigates the potential distribution characteristics and corrosion behavior of X80 steel under disbonded coatings in various soil environments using a simulated coating disbondment experimental setup, aiming to provide guidance for analyzing corrosion evolution and formulating protection strategies in disbonded regions. A self-developed adjustable disbondment simulation device was employed to examine CP potential distribution at different positions within the disbondment. Combined with characterization techniques including scanning electron microscopy (SEM) and confocal laser scanning microscopy (CLSM). The CP potential distribution along disbondment direction and localized corrosion features have been studied and analyzed in four typical soil environments: coastal saline soil, inland saline-alkali soil, red clay, and meadow soil. The key findings demonstrate: CP potential shifts positively as the extending of disbondment zone. Effective CP protection mainly concentrates around the coating defects, then the CP potential decays rapidly along disbondment zone until reaching near-free corrosion state, here the CP current would be shielded. The CP potential distribution and effective protection range are influenced by liquid film thickness within disbondment zone and soil salt content (resistivity). High-salinity, low-resistivity coastal saline soil facilitates better CP current penetration. Restricted ion diffusion/migration within confined disbondment space significantly affects spatial distribution of potential/current. Localized corrosion predominates in coastal saline soil and red clay environments, whereas uniform corrosion occurs in inland saline-alkali soil and meadow soil. Corrosion rate in disbonded regions substantially exceeds that at open coating defects..

     

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