朱建鲁, 张捷, 李玉星, 刘翠伟, 宁元星. 纯氢/掺氢管道密封圈与密封垫性能研究进展[J]. 油气储运, 2024, 43(7): 730-739. DOI: 10.6047/j.issn.1000-8241.2024.07.002
引用本文: 朱建鲁, 张捷, 李玉星, 刘翠伟, 宁元星. 纯氢/掺氢管道密封圈与密封垫性能研究进展[J]. 油气储运, 2024, 43(7): 730-739. DOI: 10.6047/j.issn.1000-8241.2024.07.002
ZHU Jianlu, ZHANG Jie, LI Yuxing, LIU Cuiwei, NING Yuanxing. Research progress on seal ring and gasket for pure hydrogen/hydrogen-enriched compressed natural gas pipeline[J]. Oil & Gas Storage and Transportation, 2024, 43(7): 730-739. DOI: 10.6047/j.issn.1000-8241.2024.07.002
Citation: ZHU Jianlu, ZHANG Jie, LI Yuxing, LIU Cuiwei, NING Yuanxing. Research progress on seal ring and gasket for pure hydrogen/hydrogen-enriched compressed natural gas pipeline[J]. Oil & Gas Storage and Transportation, 2024, 43(7): 730-739. DOI: 10.6047/j.issn.1000-8241.2024.07.002

纯氢/掺氢管道密封圈与密封垫性能研究进展

Research progress on seal ring and gasket for pure hydrogen/hydrogen-enriched compressed natural gas pipeline

  • 摘要:
    目的 密封圈与密封垫是纯氢/掺氢管道安全运行不可或缺的密封元件,探究氢环境下密封圈与密封垫的性能对于管道的安全高效输送具有重要意义。
    方法 梳理国内外关于密封圈与密封垫的研究进展,探讨分析了氢环境下常用密封材料、氢气渗透密封圈机理及伴随的吸氢膨胀现象与鼓泡断裂现象、非氢环境下垫片压缩回弹与蠕变松弛现象以及氢环境下垫片的氢脆等关键问题。
    结果 目前关于非氢环境下密封圈与密封垫的性能研究较为成熟,而纯氢或掺氢管道的发展正处于初级阶段,对于纯氢或掺氢环境下密封圈与垫片密封性能研究尚不完善,存在许多薄弱环节亟待解决。
    结论 氢气以分子形式渗透橡胶O形圈,施加气体压力与外界环境温度都会影响氢气渗透橡胶密封材料的进程,填充材料分别为炭黑与二氧化硅时橡胶材料吸氢量差异性较大,需进一步评价其他填充材料与添加剂种类对吸氢量的影响;橡胶密封材料在氢气环境下会产生体积膨胀现象,吸氢膨胀与鼓泡断裂为不同性质的体积膨胀,外界压力的突降为鼓泡断裂产生不可或缺的条件,当前鼓泡断裂主要以透明的三元乙丙橡胶为研究对象,需进一步研究其他与氢相容的橡胶材料的鼓泡断裂行为,进一步研究改变掺氢比对橡胶O形圈溶胀现象的影响规律;临氢环境下垫片的原位力学试验研究不足,需明确掺氢比与垫片力学性能参数

     

    Abstract:
    Objective Seal rings and gaskets are deemed indispensable sealing components for the safe operation of pure hydrogen/ hydrogen-enriched compressed natural gas pipelines. Therefore, investigating their performance in hydrogen environments holds great significance for the safe operation of these pipelines.
    Methods This study focused on reviewing the advancements in research concerning seal rings and gaskets both in China and abroad. It delved into pivotal aspects, including prevalent seal materials for hydrogen environments, the mechanism of hydrogen permeation through seal rings accompanied by hydrogen absorption induced swelling and blister fracture, as well as the compression resilience and creep relaxation of gaskets in non-hydrogen environments, and hydrogen embrittlement of gaskets within hydrogen environments.
    Results Current researches on the properties of seal rings and gaskets in non-hydrogen environments have achieved promising progress. However, since pure hydrogen or hydrogen-enriched compressed natural gas pipelines are still in the stage of initial development, researches on the properties of seal rings and gaskets in these environments are deficient, and many weak points relating to this area are requiring urgent care.
    Conclusion Hydrogen permeation through rubber O-rings occurs at the molecular level, and this process is influenced by gas pressure and external temperatures. Notably, carbon black and silicon dioxide, serving as filling materials, exhibit significant variations in hydrogen absorption within rubber materials. This necessitates a deeper examination of alternative filling materials and additives to understand their effects on hydrogen absorption. The volumetric expansion of rubber seal materials is observed in hydrogen environments, involving distinct mechanisms of swelling induced by hydrogen absorption and blister fracture. Acknowledging sudden drops in ambient pressure as an indispensable condition for blister fracture and transparent EPDM rubber as the main object of the blister fracture research, this paper advocates further investigation into other hydrogen-compatible rubber materials and the impact of varying hydrogen blending ratios on O-ring swelling. It also underscores the deficiency of in-situ mechanical experimental research on gaskets in contact with hydrogen, emphasizing the crucial need to establish a quantifiable relationship between hydrogen blending ratios and the mechanical performance parameters of gaskets.

     

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