滕霖, 林崴, 尹鹏博, 李卫东, 黄鑫, 李加庆, 罗宇, 江莉龙. 碳中和目标下绿氨终端站储运技术发展现状及趋势[J]. 油气储运, 2024, 43(1): 1-11. DOI: 10.6047/j.issn.1000-8241.2024.01.001
引用本文: 滕霖, 林崴, 尹鹏博, 李卫东, 黄鑫, 李加庆, 罗宇, 江莉龙. 碳中和目标下绿氨终端站储运技术发展现状及趋势[J]. 油气储运, 2024, 43(1): 1-11. DOI: 10.6047/j.issn.1000-8241.2024.01.001
TENG Lin, LIN Wei, YIN Pengbo, LI Weidong, HUANG Xin, LI Jiaqing, LUO Yu, JIANG Lilong. Development status and trends of green ammonia terminal storage and transportation technologies for achieving carbon neutrality[J]. Oil & Gas Storage and Transportation, 2024, 43(1): 1-11. DOI: 10.6047/j.issn.1000-8241.2024.01.001
Citation: TENG Lin, LIN Wei, YIN Pengbo, LI Weidong, HUANG Xin, LI Jiaqing, LUO Yu, JIANG Lilong. Development status and trends of green ammonia terminal storage and transportation technologies for achieving carbon neutrality[J]. Oil & Gas Storage and Transportation, 2024, 43(1): 1-11. DOI: 10.6047/j.issn.1000-8241.2024.01.001

碳中和目标下绿氨终端站储运技术发展现状及趋势

Development status and trends of green ammonia terminal storage and transportation technologies for achieving carbon neutrality

  • 摘要:
    目的 绿氨作为氢能的优质载体,生产工艺无碳化的优势使其成为实现碳中和目标的备选能源之一,因此绿氨终端站的布局与建设对促进氢能产业链的快速发展具有重要作用,有利于推动社会能源结构的绿色转型。
    方法 概述了氨的性质:氨作为高效的储能与储氢介质,具有高能量密度、易储运、终端站无碳排放、安全性高等特点,能够显著降低储氢、运氢、用氢的成本,并可提高能源安全性。分析了氨用于储氢与储能介质具有的能量密度高、安全、长时储能等优势,调研了全球多国的氨氢项目发展与贸易情况,论述了全球快速增长的绿氨产能及需求,总结了目前氨能的贸易现状与终端站建设情况;对比目前成熟的LNG接收站相关工艺技术,详细介绍了绿氨终端站的关键工艺及技术,包括终端站绿氨存储工艺系统、液氨蒸发气处理工艺系统、终端站加注及卸载工艺系统。
    结果 提出绿氨终端站的安全性问题,深入剖析了终端站液氨泄漏导致的毒性、燃烧爆炸性等危害,并给出了预防及防护措施。
    结论 从化肥行业到能源领域,绿氨终端站技术的研究与发展对促进绿色能源氢能的利用具有重要意义,未来绿氨终端站的数量与规模将持续增加以适应新时代的需求,同时可以考虑改造LNG接收站等大宗能源及化工品储运设施以降低成本。

     

    Abstract:
    Objective Green ammonia, produced through carbon-free processes, has emerged as a high-quality carrier of hydrogen energy and stands as an alternative energy source vital for achieving carbon neutrality. Therefore, the planning and construction of green ammonia terminals hold crucial significance in facilitating the rapid development of the hydrogen energy industry chain and promoting the green transformation of the societal energy structure.
    Methods In this paper, a concise overview of ammonia's properties and advantages was provided that ammonia, as an efficient medium for energy and hydrogen storage, was able to reduce significantly the costs associated with hydrogen storage, transportation, and consumption, and enhance overall energy security due to its particular characteristics of high energy density, easy storage and transportation, zero carbon emissions at terminals, high safety and long-term storage. Various ammonia hydrogen projects and their trading details in different countries were investigated to analyze the global growth in green ammonia production capacity and demand, and to present a review of the current status of ammonia energy trade and terminal construction. In contrast to established technologies regarding LNG terminals, key processes and technologies involved in green ammonia terminals were elaborated on in this paper, including the technological system for green ammonia storage, liquid ammonia evaporator processing, and ammonia unloading and filling.
    Results This paper emphasized safety concerns associated with green ammonia terminals, specifically addressing the toxicity and potential for combustion-induced explosibility that may arise from liquid ammonia leakage. Additionally, it provided relevant preventive and protective measures.
    Conclusion The research and development of technologies for green ammonia terminals are of great significance for enhancing the utilization of green hydrogen energy in both the chemical fertilizer and energy sectors. The evolving demands of the new era call for a continued expansion of green ammonia terminals in terms of quantity and scale in the future. Furthermore, it is suggested that the renovation of bulk storage and transportation facilities, such as LNG terminals, can be an effective approach to cost reduction.

     

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