高秋英, 管善峰, 宫如波, 刘强, 毛雷霆, 田宪凯. 塔河油田腐蚀工况下碳钢的硫酸盐还原菌腐蚀行为实验[J]. 油气储运, 2020, 39(10): 1142-1147. DOI: 10.6047/j.issn.1000-8241.2020.10.009
引用本文: 高秋英, 管善峰, 宫如波, 刘强, 毛雷霆, 田宪凯. 塔河油田腐蚀工况下碳钢的硫酸盐还原菌腐蚀行为实验[J]. 油气储运, 2020, 39(10): 1142-1147. DOI: 10.6047/j.issn.1000-8241.2020.10.009
GAO Qiuying, GUAN Shanfeng, GONG Rubo, LIU Qiang, MAO Leiting, TIAN Xiankai. Experiment on sulfate-reducing bacteria influenced corrosion of carbon steels under corrosive working conditions in Tahe Oilfield[J]. Oil & Gas Storage and Transportation, 2020, 39(10): 1142-1147. DOI: 10.6047/j.issn.1000-8241.2020.10.009
Citation: GAO Qiuying, GUAN Shanfeng, GONG Rubo, LIU Qiang, MAO Leiting, TIAN Xiankai. Experiment on sulfate-reducing bacteria influenced corrosion of carbon steels under corrosive working conditions in Tahe Oilfield[J]. Oil & Gas Storage and Transportation, 2020, 39(10): 1142-1147. DOI: 10.6047/j.issn.1000-8241.2020.10.009

塔河油田腐蚀工况下碳钢的硫酸盐还原菌腐蚀行为实验

Experiment on sulfate-reducing bacteria influenced corrosion of carbon steels under corrosive working conditions in Tahe Oilfield

  • 摘要: 为了研究塔河油田腐蚀工况条件下硫酸盐还原菌(SRB)对碳钢腐蚀行为的影响规律, 采用高温高压反应釜模拟腐蚀工况进行实验, 测试细菌数量, 利用扫描电子显微镜、激光共聚焦显微镜对腐蚀形貌和点蚀深度进行分析, 并采用失重法计算腐蚀速率。实验研究发现: ①在高矿化度(Cl-质量浓度为11.87×104 mg/L)下, 温度由40℃升至80℃, 溶液中的细菌数量, 由110个/mL减少至25个/mL; ②当温度为40℃时, 点蚀速率最大, 为5.475 mm/a; ③当温度为60℃时, 随着矿化度升高, 细菌活性降低, 点蚀速率呈现先降低后升高趋势; ④在高矿化度、60℃条件下, 改变H2S分压, 对溶液中的细菌数量无明显影响, 但点蚀速率和均匀腐蚀速率下降。研究结果表明: SRB在塔河油田极端工况下可以存活, 温度和矿化度升高可使SRB浓度降低, H2S分压对SRB浓度影响不大。温度是影响SRB腐蚀的重要因素, 温度越高, SRB造成的点蚀越轻微; 矿化度升高会影响细菌活性, 削弱细菌造成的点蚀。

     

    Abstract: In order to study the influence of sulfate-reducing bacteria(SRB) on the corrosion behavior of carbon steel under the corrosive working conditions in Tahe Oilfield, the tests were carried out by simulating the corrosive working conditions with a high temperature and high pressure autoclave to measure the bacteria counts, the corrosion morphology and pitting depth was analyzed with scanning electron microscope and laser scanning confocal microscope, and the corrosion rate was calculated using a weight loss method. The study found out that, under the condition of high salinity(the mass concentration of Cl- is 11.87×104 mg/L), the temperature rose from 40 ℃ to 80 ℃, and the bacteria counts reduced from 110 cells/mL to 25 cells/mL. The maximum pitting rate, 5.475 mm/a, occurred at 40 ℃, and at 60 ℃, the bacteria activity decreased and the pitting rate decreased at first and then rose with the salinity increase. Under 60 ℃ condition with high salinity, changing the partial pressure of H2S had no obvious effect on bacteria count in solution, but the pitting rate and uniform corrosion rate decreased. The study results indicate that SRB can survive under the extreme conditions of Tahe Oilfield, temperature rise and increasing of salinity may result in the decreasing of SRB concentration, but partial pressure of H2S has little influence on SRB concentration. Temperature is an important factor affecting SRB corrosion. The higher the temperature is, the slighter the pitting caused by SRB is. Additionally, increasing of salinity may affect the activity of bacteria, further weakening the pitting due to bacteria.

     

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