李春雨, 冯昕媛, 李本全. 微含硫天然气管道内腐蚀分析与控制[J]. 油气储运, 2019, 38(2): 202-207. DOI: 10.6047/j.issn.1000-8241.2019.02.013
引用本文: 李春雨, 冯昕媛, 李本全. 微含硫天然气管道内腐蚀分析与控制[J]. 油气储运, 2019, 38(2): 202-207. DOI: 10.6047/j.issn.1000-8241.2019.02.013
LI Chunyu, FENG Xinyuan, LI Benquan. Analysis and control on the internal corrosion of natural gas pipelines with micro-sulfur[J]. Oil & Gas Storage and Transportation, 2019, 38(2): 202-207. DOI: 10.6047/j.issn.1000-8241.2019.02.013
Citation: LI Chunyu, FENG Xinyuan, LI Benquan. Analysis and control on the internal corrosion of natural gas pipelines with micro-sulfur[J]. Oil & Gas Storage and Transportation, 2019, 38(2): 202-207. DOI: 10.6047/j.issn.1000-8241.2019.02.013

微含硫天然气管道内腐蚀分析与控制

Analysis and control on the internal corrosion of natural gas pipelines with micro-sulfur

  • 摘要: 天然气中含有少量H2S气体,若脱水不彻底,则会在管道内形成湿H2S环境,导致管体发生电化学腐蚀。以两东管道和柴北缘管道为例,利用内检测数据分析、焊接工艺评定及腐蚀机理分析等手段,对微含硫天然气管道内腐蚀机理进行分析,并提出腐蚀控制建议。不考虑内检测误差,两东管道和柴北缘管道内部管壁局部腐蚀点平均腐蚀速率分别为0.126 0 mm/a和0.008 6 mm/a,实验室腐蚀模拟试验测得工况条件下管体均匀腐蚀速率分别为0.006 9 mm/a和0.007 0 mm/a。焊接工艺分析表明金相和硬度满足相关标准要求,当前焊接工艺满足要求。相对较高的H2S含量和较湿润的环境是两东管道比柴北缘管道内局部腐蚀严重的主要原因。此类管道应该严格控制输送的天然气水露点低于环境温度5 ℃以下,同时定期清管排除管内积液,并设置腐蚀监控点,定期进行壁厚测试。

     

    Abstract: There is slight H2S in natural gas. If water and hydrocarbon are not removed thoroughly, wet H2S environment is formed inside the pipeline and consequently the pipe is suffered from electrochemical corrosion. In this paper, Liangdong Pipeline and Chaibeiyuan Pipeline were taken as the examples to analyze the internal corrosion causes and mechanisms of micro-sulfur natural gas pipelines by means of internal detection data analysis, welding procedure evaluation and corrosion mechanism analysis. And then, the suggestions on corrosion control were proposed. It is shown that the average corrosion rate at local corrosion points in the internal wall is 0.126 mm/a in Liangdong Pipeline and 0.008 6 mm/a in Chaibeiyuan Pipeline if the error of internal detection is not taken into account. According to the laboratory corrosion simulation test results, the uniform corrosion rates of Liangdong Pipeline and Chaibeiyuan Pipeline in the working conditions are 0.006 9 mm/a and 0.007 mm/a, respectively. The analysis on welding technology indicates that metallographic and hardness satisfy the related standards and requirements and the current welding technology is satisfactory. Compared with Chaibeiyuan Pipeline, the local corrosion in Liangdong Pipeline is more serious due to its higher H2S content and wetter environment. As for this type of pipeline, the water dew point of transported natural gas shall be controlled strictly 5 ℃ lower than the ambient temperature and pigging shall be carried out regularly to eliminate liquid loading. Besides, it is recommended to set corrosion monitoring points to test the wall thickness regularly.

     

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