稠油水包油型乳状液稳定性与流变性影响因素
The factors influencing the stability and rheological property of heavy O/W emulsion
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摘要: 稠油黏度高, 开采、运输难度较大, 需乳化降黏输送, 研究其乳状液特性显得尤为重要。基于单因素实验, 分析了表面活性剂类型及含量、油水比、乳化温度及乳化强度对稠油水包油(O/W)型乳状液稳定性及流变性的影响。结果表明: 不同类型表面活性剂所稳定的乳状液, 其稳定性和流变性差异较大。随着CAB-35质量分数的增加, 乳状液的分水率先降低后趋于稳定, 表观黏度先急剧增大后趋于稳定。随着油水比的增加, 乳状液分水率降低, 表观黏度逐渐增加。随着乳化温度升高, 乳状液的分水率先降低后升高, 表观黏度逐渐降低。随着乳化强度增大, 乳状液分水率逐渐减小, 表观黏度先增大后趋于稳定。综合考虑稳定性与流变性, 确定了最优乳化条件, 可为稠油O/W型乳状液的乳化降黏提供理论依据。Abstract: The viscosity of heavy oil is high, so its exploitation and transportation is more difficult.To solve this problem, its viscosity has to be reduced by means of emulsification.Therefore, it is quite important to study the characteristics of its emulsion.In this paper, the effects of surfactant type & content, oil/water ratio, emulsifying temperature and emulsifying intensity on the stability and rheological property of heavy O/W emulsion were studied by means of single-factor experiments.It is shown that the stable emulsions prepared by different types of surfactants have large differences in stability and rheological property.With the mass fraction increase of CAB-35, the water separation rate of emulsion decreases firstly and then changes insignificantly, while its apparent viscosity increases firstly and then changes insignificantly.With the increase of oil/water ratio, the water separation rate of emulsion decreases and its apparent viscosity increases gradually.With the increase of emulsifying temperature, the water separation rate of emulsion decreases firstly and then increases and its apparent viscosity decreases gradually.With the increase of emulsifying intensity, the water separation rate of emulsion decreases gradually and its apparent viscosity increases firstly and then stays at a stable value.The optimal emulsification condition was determined by considering stability and rheological property comprehensively.The research results provide the theoretical basis for the emulsification based viscosity reduction of heavy O/W emulsion.