吕一宁, 宫敬, 王嘉琪, 秦伟, 史博会. 油包水乳状液中水合物形成模型研究进展[J]. 油气储运, 2017, 36(6): 674-682. DOI: 10.6047/j.issn.1000-8241.2017.06.010
引用本文: 吕一宁, 宫敬, 王嘉琪, 秦伟, 史博会. 油包水乳状液中水合物形成模型研究进展[J]. 油气储运, 2017, 36(6): 674-682. DOI: 10.6047/j.issn.1000-8241.2017.06.010
LYU Yining, GONG Jing, WANG Jiaqi, QIN Wei, SHI Bohui. Research progress on formation model of gas hydrate in water-in-oil emulsion[J]. Oil & Gas Storage and Transportation, 2017, 36(6): 674-682. DOI: 10.6047/j.issn.1000-8241.2017.06.010
Citation: LYU Yining, GONG Jing, WANG Jiaqi, QIN Wei, SHI Bohui. Research progress on formation model of gas hydrate in water-in-oil emulsion[J]. Oil & Gas Storage and Transportation, 2017, 36(6): 674-682. DOI: 10.6047/j.issn.1000-8241.2017.06.010

油包水乳状液中水合物形成模型研究进展

Research progress on formation model of gas hydrate in water-in-oil emulsion

  • 摘要: 一旦水合物引起管道堵塞,将给深海油气资源输送安全造成严重威胁,因此,定量预测不同工况下水合物的形成尤为重要,但是目前气体水合物形成的动力学机理尚不明确。系统阐述了国内外油包水体系中水合物形成动力学的研究进展,着重介绍了气体水合物在以油相为主体的油-气-水多相体系中成核与生长的动力学模型,分析了主要模型的优点和局限性。基于油包水乳状液体系中气体水合物形成动力学的研究现状,提出多相体系中水合物形成研究应该从传质和本征反应的耦合机理入手,并结合不同尺度下的试验研究,考虑多相体系中的形成物理过程、传质与传热限制,建立适用性更广的水合物形成模型,从而为管道的流动安全提供理论支撑。

     

    Abstract: The transportation of deepwater oil and gas resources will be threatened seriously once pipelines are plugged by hydrate. Therefore, it is essential to predict quantitatively the formation of hydrate in different working conditions. At present, however, the formation kinetics mechanisms of gas hydrate are not clear. In this paper, the domestic and foreign research progress on formation kinetics of hydrate in water-in-oil systems was illustrated systematically, the kinetics model used for nucleation and growth of gas hydrate in the oil-gas-water multiphase systems with oil as the dominant phase was mainly introduced. Then, the advantages and disadvantages of main models were analyzed. Finally, based on the status of researches on formation kinetics of gas hydrate in water-in-oil emulsion systems, it was recommended to study the formation of hydrate in multiphase systems with the coupling mechanism of mass transfer and intrinsic reaction as the beginning point. And then combined with the test studies of different scales, a more applicable model for the formation of hydrate will be established by taking into consideration the physical process, mass transfer and heat transfer restriction in multiphase systems, so as to provide the assurance for the flow safety of pipelines.

     

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