范开峰, 黄启玉, 李思, 于文. 油水乳状液蜡沉积规律与扩散系数[J]. 油气储运, 2015, 34(10): 1067-1072. DOI: 10.6047/j.issn.1000-8241.2015.10.009
引用本文: 范开峰, 黄启玉, 李思, 于文. 油水乳状液蜡沉积规律与扩散系数[J]. 油气储运, 2015, 34(10): 1067-1072. DOI: 10.6047/j.issn.1000-8241.2015.10.009
FAN Kaifeng, HUANG Qiyu, LI Si, YU Wen. Wax deposition laws and diffusion coefficient of oil-water emulsion[J]. Oil & Gas Storage and Transportation, 2015, 34(10): 1067-1072. DOI: 10.6047/j.issn.1000-8241.2015.10.009
Citation: FAN Kaifeng, HUANG Qiyu, LI Si, YU Wen. Wax deposition laws and diffusion coefficient of oil-water emulsion[J]. Oil & Gas Storage and Transportation, 2015, 34(10): 1067-1072. DOI: 10.6047/j.issn.1000-8241.2015.10.009

油水乳状液蜡沉积规律与扩散系数

Wax deposition laws and diffusion coefficient of oil-water emulsion

  • 摘要: 蜡沉积问题是含蜡原油输送管路中面临的突出问题之一,而针对油水乳状液中蜡沉积问题的研究较少。以大庆原油(含水率为0)及其配置的含水率为10%、20%和30%的乳状液为实验样品,利用冷指实验装置,通过改变冷指温度、冷指和罐壁间温差以及含水率等变量,分析了油水乳状液中的蜡沉积规律。实验发现,相同温差下油壁温度降低会使蜡沉积质量增加,沉积量随含水率增大而减小。推导了蜡沉积扩散系数的计算方法,并得到了扩散系数的分布规律。平均温度的降低和含水率的升高会使扩散系数减小,高温区间下水相对扩散系数的影响比低温区间更明显。研究结果对大庆含蜡原油混输管道中蜡沉积规律的认识和清管周期的确定具有现实意义。

     

    Abstract: Wax deposition is one of the key problems that occur in waxy crude oil pipelines, but research has rarely been conducted on wax deposition of oil-water emulsion. In this paper, experiment samples are prepared with Daqing Crude Oil (water cut of 0) and its emulsions with water cut of 10%, 20% and 30%. Cold finger experiment facilities are used to analyze wax deposition laws of oil-water emulsion by changing the variants, including cold finger temperature, temperature difference between cold finger and tank wall, and water cut. It is shown by the experiment that at the same temperature difference, the volume of wax deposit rises with the decrease of oil tank temperature, but decreases with the rise of water cut. The calculation method of wax deposition diffusion coefficient is deduced and its distribution laws are obtained. Diffusion coefficient decreases with the decrease of average temperature and increase of water cut. The effect of water phase on diffusion coefficient is more in high-temperature interval than in low-temperature interval. The research findings are practically significant for understanding wax deposition laws of Daqing waxy crude oil pipelines and determining their pigging cycles.

     

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