郭海峰, 刘玮莅, 徐超, 赵德, 孙鹏飞, 代晓东, 张志恒. 防止输气管道站场设备冰堵的表面改性处理[J]. 油气储运, 2012, 31(6): 447-449. DOI: 10.6047/j.issn.1000-8241.2012.06.011
引用本文: 郭海峰, 刘玮莅, 徐超, 赵德, 孙鹏飞, 代晓东, 张志恒. 防止输气管道站场设备冰堵的表面改性处理[J]. 油气储运, 2012, 31(6): 447-449. DOI: 10.6047/j.issn.1000-8241.2012.06.011
GUO Haifeng, LIU Wei-li, XU Chao, ZHAO De, SUN Peng-fei, DAI Xiao-dong, ZHANG Zhi-heng. Ice blockage prevention for station equipments of gas pipeline by surface modification of steel material[J]. Oil & Gas Storage and Transportation, 2012, 31(6): 447-449. DOI: 10.6047/j.issn.1000-8241.2012.06.011
Citation: GUO Haifeng, LIU Wei-li, XU Chao, ZHAO De, SUN Peng-fei, DAI Xiao-dong, ZHANG Zhi-heng. Ice blockage prevention for station equipments of gas pipeline by surface modification of steel material[J]. Oil & Gas Storage and Transportation, 2012, 31(6): 447-449. DOI: 10.6047/j.issn.1000-8241.2012.06.011

防止输气管道站场设备冰堵的表面改性处理

Ice blockage prevention for station equipments of gas pipeline by surface modification of steel material

  • 摘要: 天然气管道低温输送时容易发生冰堵,影响正常的输气生产。以站场设备的冰堵防治为目的,通过冰冻实验,使用接触角测试仪、扫描电镜进行测试并结合理论分析,探索了通过表面改性方法调节站场运行设备表面的化学性质,进而防治冰堵的可行性。研究表明:适当的表面处理和硅烷改性,可以在钢表面形成一层疏水或超疏水纳米膜,增加水在其表面的接触角,使水难以在钢表面停留,同时冰冻实验也证明表面改性可以延长结冰时间;经疏水和超疏水改性后,由于接触角增大,引起水结晶成冰的形核功大幅增加,并且接触角越大,形核功越大,越难结晶成冰。实验和理论研究结果证明,钢表面疏水改性,可以解决站场设备的冰堵问题,具有应用潜力。

     

    Abstract: Ice blockage will easily occur when transporting natural gas at low temperature, which threatens the safe running of gas pipeline. Aiming at eliminating ice blockage of equipments in compressor station, the feasibility study to control ice blockage is made by a freezing test. In the test, contact angle tester and scanning electron microscope are in position. Based on theoretical analysis, surface modifying method to vary the chemical property of base metal of steel for the equipments in compressor station is reviewed. Researches indicate that proper surface treatment and silane modification on the base metal can form a layer of hydrophobic or super-hydrophobic nanometer film on the steel surface, which increases the contact angle of water on its surface with water holding free on steel surface. And moreover, the freezing test also certifies that the modified surface of steel can prolong the freezing time after hydrophobic and super-hydrophobic modification, the kernelled work of water to ice is greatly increased with the increase of contact angle. The bigger the contact angle is, the greater the kernelling work is, and the more difficult the water to ice is. The test and theory results show that hydrophobic modification of steel surface can deal with the ice blockage of equipments in compressor station with an available field application.

     

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