孙骥姝, 李鸿英, 张帆, 张劲军. 小振幅温降扫描法确定含蜡原油的胶凝温度[J]. 油气储运, 2005, 24(10): 32-35. DOI: 10.6047/j.issn.1000-8241.2005.10.009
引用本文: 孙骥姝, 李鸿英, 张帆, 张劲军. 小振幅温降扫描法确定含蜡原油的胶凝温度[J]. 油气储运, 2005, 24(10): 32-35. DOI: 10.6047/j.issn.1000-8241.2005.10.009
SUN Jishu, LI Hongying, . Determining Gelation Temperature of Waxy Crude by Small Amplitude Oscillatory Shear Temperature Sweep Experiment[J]. Oil & Gas Storage and Transportation, 2005, 24(10): 32-35. DOI: 10.6047/j.issn.1000-8241.2005.10.009
Citation: SUN Jishu, LI Hongying, . Determining Gelation Temperature of Waxy Crude by Small Amplitude Oscillatory Shear Temperature Sweep Experiment[J]. Oil & Gas Storage and Transportation, 2005, 24(10): 32-35. DOI: 10.6047/j.issn.1000-8241.2005.10.009

小振幅温降扫描法确定含蜡原油的胶凝温度

Determining Gelation Temperature of Waxy Crude by Small Amplitude Oscillatory Shear Temperature Sweep Experiment

  • 摘要: 在不破坏原油结构的前提下, 采用RS150流变仪小振幅振荡剪切温度扫描法, 对降温过程中含蜡原油粘弹性参数随温度的变化规律进行了研究。试验结果表明, 当小振幅温度扫描试验的降温速率控制在0.5-1℃/min, 储能模量(G’)和耗能模量(G”)相等时的胶凝温度与按SY/T0541-94方法测定凝点基本一致, 说明用小振幅振荡剪切温度扫描法来确定含蜡原油的凝点是可行的。

     

    Abstract: Viscoelasticity is one of the most important indexes evaluating rhelolgical properties of waxy crude oil. The gelling process of waxy crude is observed with a controlled-stress rheometer RS 150 by small amplitude oscillatory shear temperature sweep experiment, which has the advantage of a continuous evolution of the viscoelastic properties without destroying the crude inner structure. The experimental results show that the gelation temperature at which G'= G", coincides with the gel point when the temperature sweep has a cooling rate of 0. 5-1℃/min. For 14 virgin crudes and 3 PPD-beneficiated crudes with various thermal history, and 96 pairs Daqing crude with different shear history, the gelation temperatures as which G' = G" when the temperature sweep has a cooling rate of 0. 5-1℃/min are in good agreement with gel points. The absolute average deviation between the gelation temperatures and gel points for 113 pairs of compared data is only 0. 5℃, in which the absolute deviation of 110 pairs, that is 97. 3% of the compared pairs, is less than 1℃, the absolute deviation of others 7 pairs is greater than 1℃ but less than 2℃. These results suggest that the gel point of waxy crude can be determined by small amplitude oscillatory shear temperature shear temperature sweep experiment.

     

/

返回文章
返回