罐车装运喷气燃料银片腐蚀不合格的研究
Investigation of Silver Strip Corrosion on Jet Fuels Subject to Contaminated RailContainers
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摘要: 针对喷气燃料装入罐车后银片腐蚀不合格的问题进行了研究, 研究结果表明, 主要原因是罐车内含有元素硫, 这些元素硫主要来源于罐壁硫腐蚀反应, 目前采用特殊清洗工艺也不能完全将其洗掉。建立了汞滴法测定元素硫的相对含量, 其测定结果与油品银片腐蚀具有较好的一致性。当罐底残油元素硫含量大于10μg/g(汞滴10min变色)时, 罐车特殊清洗后也可使其装运的喷气燃料银片腐蚀不合格, 因此在罐车特殊清洗前, 采用汞滴法快速测定罐车残油中的元素硫含量, 经检测后不合格的罐车不能用于装运喷气燃料, 从而有效地解决了罐车致使喷气燃料银片腐蚀不合格的问题。Abstract: In some cases, severe corrosion are found during silver strip testing to the jet fuels that are charged to rail containers. Investigation shows that the disqualifying corrosion attributes to elementary sulfur remained in the inner surface of the containers. The actual cleaning-up measurements are not sufficient to remove all the harmful sulfur from the surfaces. Comparative study indicates high relativity between silverstrip corrosion and sulfur content detected in the method of mercury dropping. When sulfur content of the residual oil at the container bottom exceeds 10 μg/g (mercury drop color change in 10 min), the silver strip corrosion test will surely come forth with disqualification of the jet fuels even though the containers are extensively cleaned up. So mercury drop test of container residuals is a rapid and flexible and economical way to determine container's applicability for further jet fuel transportation. Contaminated containers can be predefine by mercury dropping test before cleaning resulting in better assured fuel quality.