超临界CO2往复式压缩机排气管路气流脉动分析与优化

Analysis and optimization of gas pulsation in the exhaust pipeline of supercritical CO2 reciprocating compressors

  • 摘要:
    目的 超临界CO2广泛应用于新型能源系统及CCUS(Carbon Capture, Utilization and Storage)过程。压缩机作为连接CCUS捕集端与封存端的关键设备,其排气过程中超临界CO2易发生剧烈脉动,进而诱发管路振动,严重时甚至导致结构疲劳与管道破坏。因此,针对超临界CO2往复式压缩机开展气流脉动分析与优化对于提高系统运行的稳定性与安全性极为重要。
    方法 采用基于真实气体状态方程的数值模拟方法,结合多组典型工况参数,系统分析超临界CO2往复式压缩机排气条件及管路结构对气流脉动特性的影响,对比不同排气压力、排气温度、CO2质量分数及排气管路直径下的脉动响应,提出基于滤波管结构模型的参数设计方法。
    结果 超临界CO2气流脉动呈现出不同于常规气体的特殊行为特征。由于超临界CO2密度较高,而黏度较小,更易形成湍流脉动,其在30 MPa排气压力下的脉动幅度远高于CH4,且存在明显的双波峰结构。随着排气压力由10 MPa增至30 MPa,排气管路压力不均匀度与脉动能量均显著增大,更易导致管路振动;随着排气温度由403 K升高至453 K,系统在403 K与413 K下更易进入共振区间,气流扰动明显增强;CO2质量分数升高,压力脉动幅值随之扩大,但峰值频率不变,易发生共振。结构参数对脉动控制效果影响显著,当排气管路直径增大至160 mm以上时,能有效降低压力不均匀度与脉动能量,但对峰值频率的影响较小;滤波管直径控制在40 mm左右,可兼顾压力损失与脉动抑制效果。
    结论 揭示了超临界CO2往复式压缩机中气流脉动的关键影响因素及作用机理,提出了基于管路结构参数优化的调控策略,研究成果可为超临界CO2压缩系统的工程设计与安全运行提供理论支撑。

     

    Abstract:
    Objective Supercritical CO2 is widely used in new energy systems and Carbon Capture, Utilization and Storage (CCUS) processes. As a critical link between capture and storage, the compressor experiences severe supercritical CO2 pulsations during the exhaust process, causing pipeline vibrations that may lead to structural fatigue and pipeline damage in severe cases. Therefore, analyzing and optimizing gas pulsations in supercritical CO2 reciprocating compressors is essential to enhance system stability and safety.
    Methods A numerical simulation method based on the real-gas equation of state was employed to systematically analyze the effects of exhaust conditions and pipeline structure on gas pulsation characteristics of the supercritical CO2 reciprocating compressor using multiple sets of typical operating parameters. Pulsation responses under varying exhaust pressures, temperatures, CO2 mass fractions, and pipe diameters were compared, and a parameter design method leveraging the filter tube structure model was proposed.
    Results The gas pulsation of supercritical CO2 exhibited distinct characteristics compared to conventional gases. Turbulent pulsation was more likely to form due to its high density and low viscosity. At an exhaust pressure of 30 MPa, the pulsation amplitude was significantly higher than that of CH4, displaying a pronounced double-peak structure. As the exhaust pressure increased from 10 MPa to 30 MPa, both pressure non-uniformity and pulsation energy in the exhaust pipeline rose markedly, increasing pipeline vibration. When exhaust temperature rose from 403 K to 453 K, the system was more prone to resonance at 403 K and 413 K, with gas flow disturbances intensifying. Increasing the CO2 mass fraction expanded pulsation amplitude without altering peak frequency, thereby raising resonance likelihood. Structural parameters significantly influenced pulsation control, evidenced by that the pressure non-uniformity and pulsation energy were effectively reduced when the exhaust pipe diameter increased beyond 160 mm, though peak frequency was minimally affected. Controlling the filter tube diameter at around 40 mm balanced pressure loss and pulsation suppression.
    Conclusion This study identifies the key factors and mechanisms influencing gas pulsation in supercritical CO2 reciprocating compressors, proposes a control strategy based on optimizing pipeline structural parameters, and offers theoretical support for the design and safe operation of supercritical CO2 compression systems.

     

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