纯氢及掺氢天然气管输系统消氢防爆技术研究进展及展望

Research progress and prospects of hydrogen elimination and explosion-proof technologies for pure hydrogen and hydrogen-blended natural gas pipeline transportation systems

  • 摘要:
    目的 在全球能源转型及“双碳”目标下,氢能作为清洁能源载体应用前景广阔,但纯氢及掺氢天然气管输系统的氢气泄漏存在高燃爆风险,亟需对消氢防爆抑爆技术进行全面探究以保障安全输送。
    方法 通过文献调研及综述分析的方法,系统归纳了消氢技术、被动与主动防护技术、抑爆技术的科学原理,评估了各类技术的消氢抑爆效能、适用场景及局限性,重点剖析了多介质协同消氢抑爆的创新模式,并梳理了国内外最新研究成果与工程案例。
    结果 在消氢技术方面,开放空间中通风方式的效果受限,惰化法虽抑爆效果好但规模化成本与安全风险并存,催化消氢效率高却面临催化剂抗毒化能力不足的挑战,而多级协同消氢体系(如通风+惰化+催化)可显著提升安全性与消氢效率。在阻爆及泄压技术方面,主动式阻爆响应快但设备可靠性要求高,被动式阻爆需针对氢气特性优化结构,泄压技术受泄放口尺寸、气体浓度影响显著,需防范二次燃爆。单一抑爆技术均存在局限性,惰性气体抑爆需高浓度支撑、液相抑爆存在设备腐蚀风险、粉体抑爆在纯氢环境中效果有限、多孔材料抑爆面临材料选型及适应性等挑战,而协同抑爆技术通过多种抑爆剂的协同作用,可显著提升抑爆效果。
    结论 当前消氢防爆抑爆技术仍面临成本高、材料适应性不足及复杂工况稳定性差等挑战,未来需发展“高效消氢+多介质抑爆”的协同模式,研发低成本耐毒化催化剂、智能调控系统及吸氢靶向材料,优化抑爆介质配方,建立场景化安全标准,为氢能管道输运系统的安全运行提供技术参考。

     

    Abstract:
    Objective Amid the global energy transition and the “dual-carbon” goals, hydrogen energy, as a clean energy carrier, holds significant application potential. However, hydrogen leakage in pure hydrogen and hydrogen-blended natural gas pipeline transportation systems poses a high explosion risk. Therefore, it is imperative to advance comprehensive hydrogen elimination, explosion prevention, and explosion suppression technologies to ensure safe transportation.
    Methods Through literature research and review analysis, the scientific principles of hydrogen elimination, passive and active protection, and explosion suppression technologies were systematically summarized. The effectiveness, applicable scenarios, and limitations of these technologies were evaluated. The innovative model of multi-medium collaborative hydrogen elimination and explosion suppression was analyzed in detail, alongside a compilation of the latest domestic and international research findings and engineering cases.
    Results In terms of hydrogen elimination technologies, ventilation in open spaces was found to have limited effectiveness. While inerting provided effective explosion suppression, it involved high costs and safety risks. Catalytic hydrogen elimination demonstrated high efficiency but faced challenges with catalyst poisoning. A multi-stage collaborative hydrogen elimination system (such as ventilation combined with inerting and catalysis) significantly improved both safety and efficiency. For explosion-proof and pressure-relief technologies, active explosion-proof systems offered rapid response but required high equipment reliability, while passive systems needed structural optimization for hydrogen characteristics. Pressure-relief effectiveness was significantly influenced by relief outlet size and gas concentration, and secondary explosions needed to be prevented. Each single explosion suppression technology had limitations: inert gas suppression required high concentrations, liquid-phase suppression risked equipment corrosion, powder suppression was less effective in pure hydrogen, and porous material suppression faced issues with material selection and adaptability. Collaborative explosion suppression technologies significantly enhanced effectiveness through the synergistic action of multiple suppressants.
    Conclusion Current hydrogen elimination, explosion prevention, and explosion suppression technologies face challenges including high costs, limited material adaptability, and poor stability under complex conditions. Future efforts should focus on developing a collaborative model of efficient hydrogen elimination combined with multi-medium explosion suppression. This includes developing low-cost, anti-poisoning catalysts, intelligent control systems, and targeted hydrogen-absorbing materials, optimizing explosion suppression formulations, and establishing scenario-based safety standards to guide the safe operation of hydrogen pipeline transportation systems.

     

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