天然气在线色谱载气分流与多流路优化应用

Application of carrier gas splitting and multi-flow-path optimization for online natural gas chromatography

  • 摘要:
    目的 在线气相色谱仪是天然气能量计量与贸易结算的核心设备,传统系统普遍采用昂贵的氦气作为分离载气与阀门驱动气源。阀门驱动可消耗高达70%~75%的氦气,造成严重的资源浪费。为解决该问题,降低氦气消耗并提升设备的综合利用率,开展了基于载气分流与多流路协同设计的优化方法研究。
    方法 以主流在线气相色谱仪为研究对象,对气路系统进行模块化改造,在物理层面实现载气与驱动气的完全解耦。选用低成本的高纯氮气或天然气替代氦气作为独立驱动气源,并采用质量流量控制器实施精确调节。同时,设计并接入多通道自动进样系统,结合高频低死体积电磁阀结构,引入“吹扫-隔离-进样”三阶段时序控制逻辑与动态流量补偿策略,实现单台色谱仪对多路气源样品的连续自动化监测。
    结果 实验与现场验证表明,采用氮气驱动时,阀门动作耗气量可精准控制在约100 mL/周期,正异丁烷分离度达2.2,温度稳定性优于±0.3℃,各项核心性能均符合GB/T 13610—2020《天然气的组成分析气相色谱法》及JJG 1055—2009《在线气相色谱仪检定规程》。多流路切换测试显示,在30 s吹扫条件下系统交叉污染率可降至0.1%以下。现场应用数据显示,单站年均氦气消耗量降幅达78.3%,年均运行总成本降低73.8%;多流路系统使用单台设备可替代多台传统设备的功能,改造成本在4个月内即可收回。
    结论 该载气分流与多流路协同优化技术,在确保分析精度与系统稳定性的前提下,成功解决了色谱仪高耗能与低利用率的工程难题。该方法不仅为在役天然气在线色谱仪提供了低成本、高回报的标准化改造方案,还具有极强的工业推广价值。为石化、环保领域在线分析仪器“一机多用”与低碳化运行提供了重要技术借鉴。

     

    Abstract:
    Objective Online gas chromatographs are core equipment for energy metering and trade settlement of natural gas. Traditional systems commonly use expensive helium as both the separation carrier gas and the valve driving gas; valve actuation can consume as much as 70–75% of the helium, resulting in substantial resource waste. To reduce helium consumption and improve overall equipment utilization, this study develops a solution based on carrier gas splitting and multi-flow-path collaborative optimization.
    Methods By modularizing the gas path system of mainstream online gas chromatographs, the carrier and driving gases are physically decoupled. Low-cost, high-purity nitrogen or natural gas is used to replace helium as the independent driving-gas source, with a mass-flow controller added for precise regulation. Additionally, a multi-path automatic sampling system is integrated. Based on the solenoid valve structure that facilitates high-frequency actuation and low dead volumes, a three-stage sequential control logic (purge → isolate → sample) and a dynamic flow compensation strategy are implemented. This configuration enables a single chromatograph to perform continuous automatic monitoring of samples from multiple gas sources.
    Results Experiments and field verification showed that when nitrogen was used for valve actuation, gas consumption was controlled at approximately 100 mL per cycle, the resolution of n-butane and isobutane reaches 2.2, and temperature stability was better than ±0.3 °C. All core performance indicators met the requirements of GB/T 13610-2020 (Analysis of Natural Gas Composition — Gas Chromatography) and JJG 1055-2009 (Verification Regulation of On-Line Gas Chromatograph). Multi-flow-path switching tests demonstrated that cross-contamination could be reduced to below 0.1% with 30-second purging. Field application data showed that average annual helium consumption per station decreased by 78.3% and average annual total operating cost declined by 73.8%; a single unit of the developed equipment functioned as a multi-flow-path system replacing multiple traditional devices, with the retrofit cost recoverable within four months.
    Conclusion The proposed carrier gas splitting and multi-flow path collaborative optimization provide a successful chromatograph solution to the engineering problems of high energy consumption and low utilization rate while ensuring the required analytical accuracy and system stability. This solution offers a low-cost, high-return standardized retrofit approach for in-service online natural-gas chromatographs and has strong potential for wider industrial deployment. The study results supply an important technical reference for implementing the concept of “multiple-purpose machines” and low-carbon operation for online analytical instruments in the petrochemical and environmental protection fields.

     

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