含蜡原油磁场降黏机理研究进展

A critical review on the viscosity reduction mechanisms of magnetically-treated waxy crude oil

  • 摘要:
    目的 常温环境下,含蜡原油因蜡晶析出形成三维网状结构,导致流动性显著下降,给原油生产与管输带来巨大的流动保障挑战。磁场处理是一种物理的原油改性方法,能够降低含蜡原油黏度,改善原油低温流动性。这一方法易于实施,但其机理复杂,降黏效果可随磁场强度、作用时间等条件非单调变化。明确含蜡原油磁场降黏机理,是推进该技术研究与应用的关键。
    方法 通过系统的文献调研,归纳原油磁场处理降黏特性,系统总结了目前已有的含蜡原油磁场降黏机理假说,并基于磁流变学、分散体系流变学等理论对磁致颗粒聚集、分散、取向排列、分子间作用力变化等机理假说进行了分析,以明确其科学性与合理性。
    结果 磁场作用下颗粒的微观形貌变化(如聚集、分散或取向排列),不是产生降黏效果的主要原因:一方面,液态含蜡原油中蜡晶浓度通常较低(小于3%),蜡晶粒径变化对黏度影响有限。另一方面,现有实验表明,磁场处理后,蜡晶粒径既可能增大也可能减小,却均伴随降黏效果。此外,蜡晶虽具有抗磁性,但由于其磁化率低,常规磁场作用下,产生的作用力远小于范德华力,因此不足以直接改变蜡晶间的作用力实现降黏。磁场最有可能是通过影响胶质、沥青质的分散状态,间接影响蜡晶与胶质、沥青质的相互作用以及蜡晶的生长过程,进而影响蜡晶间的相互作用,从而产生降黏效果。
    结论 未来可借助Zeta电位、小角X射线散射等技术手段,直接表征蜡晶表面吸附行为,并加强交变磁场、磁场增黏反常现象以及剪切-温变耦合场中降黏效果稳定性的研究。同时应发展多尺度模拟方法,从影响原油石蜡颗粒/分子间作用力的角度,对磁场改性机理进行深入研究。

     

    Abstract:
    Objective At ambient temperatures, waxy crude oil experiences a significant decline in fluidity due to the precipitation of wax crystals that form a three-dimensional network structure, posing major flow assurance challenges for oil production and pipeline transportation. Magnetic treatment, a physical modification method, can reduce viscosity and improve low-temperature fluidity of waxy crude oil. While this method is easy to implement, its underlying mechanism is complex, and the viscosity reduction effect varies non-monotonically with factors such as the magnetic field intensity and action time. Therefore, clearly understanding the mechanism of magnetic treatment is essential to advance its research and application.
    Methods The viscosity-reducing effects of magnetic treatment on crude oil were summarized through a systematic literature review. Existing hypotheses regarding the mechanisms of viscosity reduction in magnetically-treated waxy crude oil were collated, drawing on theories such as magnetorheology and dispersion system rheology. Hypotheses involving magnetic-induced particle aggregation, dispersion, alignment, and changes in intermolecular forces were analyzed to evaluate their scientific validity and rationality.
    Results Changes in the microscopic morphology of particles—such as aggregation, dispersion, or alignment—under a magnetic field are unlikely to be the primary driver of viscosity reduction. This is partly because the concentration of wax crystals in liquid waxy crude oil is typically low (< 3%), limiting the influence of crystal size variation on viscosity. Additionally, experimental results indicate that wax crystal size may increase or decrease after magnetic treatment, yet viscosity reduction is observed in both scenarios. Although wax crystals are diamagnetic, their low magnetic susceptibility means the force generated under conventional magnetic fields is much weaker than van der Waals forces and insufficient to directly alter interactions between wax crystals. It is most likely that the magnetic field influences the dispersion of resins and asphaltenes, indirectly affecting their interaction with wax crystals and the growth process of wax crystals, thereby producing the viscosity reduction effect.
    Conclusion Future research should employ techniques like Zeta potential and small-angle X-ray scattering to directly characterize wax crystal surface adsorption. Studies on alternating magnetic fields, the anomalous viscosity increase under magnetic field action, and the stability of viscosity reduction under shear-temperature coupled fields should be intensified. Additionally, multi-scale simulation methods should be developed to investigate how magnetic fields affect inter-particle and intermolecular forces among paraffinic constituents in crude oil.

     

/

返回文章
返回