基于载气分流与多流路设计的在线气相色谱分析方法研究与现场评估

Research and Field Evaluation of an Online Gas Chromatographic Analytical Method Based on Carrier-Gas Splitting and Multi-Stream Design

  • 摘要: 气相色谱仪在天然气能量计量与贸易结算中具有重要作用,但传统系统普遍使用氦气作为载气及阀门驱动气源,导致运行成本较高。为降低氦气消耗并提升设备利用率,本文提出一种基于载气分流与多流路优化设计的气相色谱分析方法。该方法通过气路系统改造,实现载气分离与驱动气功能的物理解耦,并以氮气或天然气替代氦气作为驱动气源;同时设计多流路自动进样系统,使单台色谱仪可实现多气源、多组分的在线分析。实验结果表明,在零级氮气驱动条件下,阀门启动气体消耗量稳定在约100 mL/周期,柱温与检测器温度稳定性优于 ±0.3 ℃;现场验证显示,改造后的 EMERSON 570 与 370XA 系列色谱仪性能均符合 GB/T 13610 和 JJG 1055 标准要求。研究结果表明,该方法在保证分析准确性与稳定性的同时,显著降低运行成本并提高仪器利用率,具有良好的经济与推广价值。

     

    Abstract: Gas chromatographs (GCs) play a crucial role in natural gas energy metering and trade settlement; however, conventional systems generally employ helium as both the carrier and valve-driving gas, resulting in high operational costs. To address this issue, a novel online GC analytical method based on carrier-gas splitting and multi-stream optimization is proposed. The method physically decouples the carrier gas and valve-driving functions by modifying the gas circuit and replacing helium with nitrogen or natural gas. Furthermore, a multi-stream sampling system is introduced, enabling a single GC unit to perform simultaneous online analyses of multiple gas sources and components. Experimental results indicate that under zero-grade nitrogen driving, valve actuation gas consumption is maintained at approximately 100 mL per cycle, while column and detector temperature stability are within ±0.3 °C. Field tests on EMERSON 570 and 370XA chromatographs confirm that the modified system meets the requirements of GB/T 13610 and JJG 1055 standards. This method substantially reduces helium consumption, operational costs, and equipment investment while maintaining analytical accuracy and stability, demonstrating significant economic benefits and strong potential for large-scale industrial applications in the natural gas sector.

     

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