耦合蒸汽甲烷重整和LNG冷能的氢液化工艺设计与优化

Process design and optimization of hydrogen liquefaction process coupling steam methane reforming and LNG cold energy

  • 摘要: 【目的】氢气作为一种清洁、燃烧零排放的二次能源,在我国能源转型中发挥着重要作用。将氢气液化进行储运是提高氢气储运效率最重要的方式之一,然而,氢气液化是一种能量密集型工艺,具有较高的比能耗和较低的㶲效率。【方法】为降低氢液化工艺的能耗,提高工艺的液化能效,基于国内某LNG接收站,设计一种使用LNG冷能预冷、氦Brayton循环深冷的氢液化工艺,工艺液氢产量为300吨/天。工艺以LNG气化后的天然气为原料,通过耦合蒸汽甲烷重整工艺生产氢气,并通过液化回收副产物二氧化碳为后续制作干冰提供原材料。基于设计的工艺,使用HYSYS软件和粒子群优化算法进行建模和优化,并对工艺进行能量分析、换热分析、㶲分析和热力学分析。【结果】结果表明,通过回收膨胀功,优化后工艺的比能耗、㶲效率和性能系数分别为4.797 kWh/kg、65.44%和0.276,展现较高的液化性能。㶲分析表明工艺总㶲损失为58589.63 kW,其中,正仲氢反应器和换热器具有较高的㶲损失,共占总㶲损失的56.27%。工艺中设备的㶲效率以换热器和压缩机为最高,而膨胀机由于较低的膨胀温度导致㶲效率较低。换热器复合曲线分析表明由于冷能分配合理,深冷换热器表现出较高的换热效率。【结论】该工艺在满足LNG气化外输压力的同时实现氢气的生产和高效液化,本研究对于未来LNG冷能利用和设计高效的氢液化工艺具有重要的参考价值。

     

    Abstract: Purpose As a clean secondary energy source with zero-emission combustion, hydrogen plays a significant role in China's energy transition. Liquefying hydrogen for storage and transportation is one of the most crucial methods to enhance its storage and transportation efficiency. However, hydrogen liquefaction is an energy-intensive process characterized by high specific energy consumption and low exergy efficiency. Method To reduce energy consumption and improve the liquefaction energy efficiency of the hydrogen liquefaction process, a process was designed based on a domestic LNG receiving terminal. This process utilizes LNG cold energy for precooling and a helium Brayton cycle for deep refrigeration, with a liquid hydrogen production capacity of 300 tons per day. The process utilizes natural gas from LNG vaporization as feedstock, producing hydrogen through steam methane reforming process. The by-product carbon dioxide is recovered through liquefaction to provide raw material for subsequent dry ice production. Based on the designed process, the process was modeled and optimized using HYSYS software and a particle swarm optimization algorithm. Analyses were conducted including energy analysis, heat exchange analysis, exergy analysis, and thermodynamic analysis. Results The results indicate that by recovering expansion work, the optimized process achieves a specific energy consumption, exergy efficiency, and coefficient of performance of 4.797 kWh/kg, 65.44%, and 0.276, respectively, demonstrating high liquefaction performance. Exergy analysis shows the total exergy loss of the process is 58589.63 kW. The ortho-para hydrogen converter and the heat exchangers contribute the most to this loss, accounting for 56.27% of the total. Among the equipment, heat exchangers and compressors exhibit the highest exergy efficiency, while expanders show lower exergy efficiency due to their low expansion temperatures. Composite curves analysis of the heat exchangers reveals that the cryogenic heat exchangers achieve high heat transfer efficiency owing to rational cold energy distribution. Conclusion This process realizes both hydrogen production and efficient liquefaction while satisfying the pressure requirements for LNG gasification and pipeline export. This study provides valuable insights for future utilization of LNG cold energy and the design of efficient hydrogen liquefaction processes.

     

/

返回文章
返回