氢环境下高钢级管道环焊缝断裂损伤本构模型构建

A constitutive model for fracture and damage of high-grade pipeline steel girth welds in hydrogen environments

  • 摘要:
    目的 掺氢天然气输送使高钢级管道面临氢致断裂风险,环焊缝的组织与力学性能不均匀使其成为管道结构完整性的薄弱部位。针对现有模型难以同时描述多类型氢陷阱、应力辅助扩散及损伤全过程的问题,亟需开展氢环境下高钢级管道环焊缝断裂损伤评估。
    方法 基于Oriani平衡理论、氢扩散控制方程及质量守恒关系,提出晶格氢及位错、碳化物、马氏体晶界陷阱捕获氢浓度计算方法,将浓度梯度、静水应力梯度及塑性应变引起的位错陷阱密度演化纳入扩散方程。在完全高森模型基础上,引入晶格氢与捕获氢对空隙成核、生长的加速作用,并以氢软化后的基体流变应力修正Thomason聚结判据,建立氢环境下高钢级管道环焊缝断裂损伤本构模型。通过用户材料热传导子程序、用户材料子程序及用户外部数据库子程序,实现氢扩散、应力、塑性变形及损伤演化的联合计算,并采用二维紧凑拉伸有限元算例与环焊缝阻力曲线试验进行验证。
    结果 在应力强度因子为30 MPa·m0.5、边界氢浓度为2.659×1022 m−3的CT(Compact Tension)试样算例中,所建模型再现了裂尖总氢及3类陷阱捕获氢的富集与分布情况,其变化趋势与已有研究结果一致。在室温、总压力10 MPa(H2与N2的分压分别为2 MPa与8 MPa)及加载速率0.01 mm/min条件下,经33次加卸载循环得到掺氢比为20%的环境下环焊缝阻力曲线,以裂纹扩展量0.2 mm偏置线确定的断裂韧度为0.245 7 mm;氢环境下高钢级管道环焊缝断裂损伤本构模型预测曲线与试验结果的平均相对误差仅为8%。
    结论 裂尖氢富集与断裂损伤由静水应力、塑性变形及陷阱捕获共同控制,新构建的氢环境下高钢级管道环焊缝断裂损伤本构模型能够表征不同赋存状态氢对空隙成核、生长及聚结的影响,可为掺氢管道环焊缝裂纹扩展预测与安全评价提供参考。

     

    Abstract:
    Objective Transporting hydrogen-blended natural gas exposes high-grade steel pipelines to hydrogen-induced fracture. Girth welds serve as structural weak points due to their heterogeneous microstructure and inconsistent mechanical performance. To address existing model limitations in simultaneously capturing multiple hydrogen trap types, stress-assisted diffusion, and full damage evolution, there is an urgent need to conduct fracture and damage assessments of high-grade steel pipeline circumferential welds in a hydrogen environment.
    Methods Based on Oriani’s equilibrium theory, hydrogen diffusion governing equations and mass conservation, this study proposes a calculation approach to quantify the concentrations of lattice hydrogen, alongside hydrogen trapped by dislocations, carbides and martensitic grain boundaries. The evolution of dislocation trap density induced by concentration gradients, hydrostatic stress gradients and plastic strains is incorporated into the diffusion governing equations. On the basis of the complete Gurson model, this work introduces the acceleration effect of lattice hydrogen and trapped hydrogen on void nucleation and growth. The Thomason void coalescence criterion is modified with the hydrogen-softened matrix flow stress, thereby establishing the constitutive model for fracture damage of girth welds in high-grade pipeline steels under hydrogen environments. Coupled computations of hydrogen diffusion, stress, plastic deformation, and damage evolution are realized via the User Material Heat Transfer Subroutine (UMATHT), User Material Subroutine (UMAT), and User External Database Subroutine (UEXTERNALDB). The proposed model is verified using a two-dimensional Compact Tension (CT) finite-element case and Resistance Curve (R-curve) experiments of girth welds.
    Results For the CT specimen case with a stress intensity factor of 30 MPa·m0.5 and a boundary hydrogen concentration of 2.659×1022 m−3, the proposed model reproduces the enrichment and spatial distribution of total hydrogen and hydrogen trapped by three categories of traps at the crack tip. The variation trends are consistent with those from existing research. At room temperature, a total pressure of 10 MPa (partial pressures of H2 and N2 are 2 MPa and 8 MPa, respectively) and a loading rate of 0.01 mm/min, the girth weld R-curve under the environment with a 20% hydrogen blending ratio is obtained after 33 loading-unloading cycles. The fracture toughness determined by the 0.2 mm crack growth offset line is 0.2457 mm. The average relative error between the prediction curve of the constitutive model for fracture damage of girth welds in high-grade pipeline steels under hydrogen environments and experimental data is approximately 8%.
    Conclusion Hydrogen enrichment and fracture damage at the crack tip are jointly governed by hydrostatic stress, plastic deformation and hydrogen trapping effects. The newly developed constitutive model can quantify how hydrogen in different existing states affects void nucleation, growth and coalescence for high-grade pipeline girth welds under hydrogen exposure. This model provides references for crack propagation prediction and structural integrity evaluation of girth welds of hydrogen-blended pipelines.

     

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