含蜡原油磁场降黏机理研究进展

A critical review on the viscosity reduction mechanisms of magnetically-treated waxy crude oil

  • 摘要: 【目的】常温环境下,含蜡原油流动性差,给原油生产和管输带来了巨大的流动保障挑战。磁场处理是原油的一种物理改性方法,易于实施,但机理复杂,改性效果也可随磁场强度、作用时间等条件非单调变化。明确含蜡油磁场改性机理,是推进该技术研究与应用的必由之路。【方法】通过系统的文献调研,在归纳出原油磁场处理降黏特性的基础上,系统总结了目前已有的含蜡原油磁场降黏机理假说,并基于磁流变学、分散体系流变学等理论进行了分析。【结果】分析认为,磁场作用下颗粒的微观形貌变化(如聚集、分散或取向排列),应该不是产生降黏效果的主要原因;蜡晶具有一定的抗磁性,但由于其磁化率低,磁场作用不足以直接改变蜡晶间的作用力实现降黏;磁场最有可能是通过影响胶质、沥青质状态,间接影响它们与蜡晶的相互作用,进而影响蜡晶间的相互作用,从而产生改性效果。【结论】未来可从影响原油石蜡颗粒/分子间作用力的角度,对磁场改性机理进行深入研究。(图9,表1,参73)

     

    Abstract: Objective At ambient temperatures, the poor flowability of waxy crude oils presents significant flow assurance challenges for oil production and pipeline transportation. Magnetic treatment represents a physical modification method for crude oil that is relatively easy to implement. However, the underlying mechanisms are complex, and the magnetorheological effects are not consistently correlated with factors such as the strength and duration of the magnetic field. Clearly elucidating the mechanism of magnetic treatment for waxy crude oils is therefore an essential prerequisite for advancing the research and application of this technology. Methods Through a systematic review of the existing literature, this study summarizes the viscosity-reducing characteristics of crude oil subjected to magnetic treatment. Building upon this foundation, it systematically synthesizes the current hypotheses concerning the mechanisms of viscosity reduction of magnetically treated waxy crude oil. These hypotheses are critically analyzed using established theories, including magnetorheology and the rheology of dispersed systems. Results The analysis suggests that microscopic morphological alterations of particles, such as aggregation, dispersion, or alignment induced by the magnetic field, are likely not the primary cause of the observed viscosity reduction. While wax crystals exhibit diamagnetic behavior, their low magnetic susceptibility renders the direct alteration of interparticle forces between them by the magnetic field insufficient to achieve significant viscosity reduction. The prevailing evidence indicates that the magnetic field most probably exerts its modification effect indirectly. This is achieved by influencing the state and behavior of resins and asphaltenes, which subsequently alters their interactions with the wax crystals and, ultimately, modifies the interactions between the wax crystals themselves. Conclusion Future research aimed at deepening our understanding of the magnetic modification mechanism should prioritize investigating how magnetic fields influence the inter-particle or inter-molecular forces between paraffinic constituents in crude oil.

     

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