张志荣,陈朋超,蔡永军,等. 油气泄漏多组分标志性气体浓度光谱监测方法[J]. 油气储运,2025,44(7):774−783. DOI: 10.6047/j.issn.1000-8241.2025.07.006
引用本文: 张志荣,陈朋超,蔡永军,等. 油气泄漏多组分标志性气体浓度光谱监测方法[J]. 油气储运,2025,44(7):774−783. DOI: 10.6047/j.issn.1000-8241.2025.07.006
ZHANG Zhirong, CHEN Pengchao, CAI Yongjun, et al. Spectral monitoring technology for gas concentrations of multiple target components in oil and gas leakage detection[J]. Oil & Gas Storage and Transportation, 2025, 44(7): 774−783. DOI: 10.6047/j.issn.1000-8241.2025.07.006
Citation: ZHANG Zhirong, CHEN Pengchao, CAI Yongjun, et al. Spectral monitoring technology for gas concentrations of multiple target components in oil and gas leakage detection[J]. Oil & Gas Storage and Transportation, 2025, 44(7): 774−783. DOI: 10.6047/j.issn.1000-8241.2025.07.006

油气泄漏多组分标志性气体浓度光谱监测方法

Spectral monitoring technology for gas concentrations of multiple target components in oil and gas leakage detection

  • 摘要:
    目的 传统油气泄漏气体监测方法存在检测灵敏度低、校准周期短、误报多、测量气体单一、易受环境干扰、传感器带电等问题,难以满足日益发展的智慧管网安全运维的需求,亟需构建适用于新型复杂场景的油气泄漏监测方法。
    方法 面向油气管网储运场景中的一二次密封、浮舱、隧道、地下空间、分析室等多类型受限空间场景,选取可燃气体(甲烷、丙烷、丁烷)、助燃气体(氧气)以及温度等多参数同时监测作为目标,设计了用于满足现场布设的新型全光纤耦合、本质安全、可组网的扩散式传感器探头;参考复杂体系的光谱解析与背景噪声扣除的设计思想,将传统的可调谐半导体激光吸收光谱技术(Tunable Diode Laser Absorption Spectroscopy, TDLAS)与偏最小二乘算法、非负最小二乘算法、人工智能算法模型等相结合,分别选取−761.0 nm、−1 653.0 nm、−1 686.1 nm、−1 686.5 nm作为氧气、甲烷、丙烷、丁烷的中心吸收谱线,提出了烷烃类气体分子测量时混叠吸收光谱干扰处理的共性技术,并研制了适用于多种场合的油气泄漏多组分气体浓度测量传感器。
    结果 新研制的传感器系统可以实现远距离、安全、稳定的多组分气体及其温度的实时监测与分析,能够适应多种不同应用场景的气体监测需求。经过实验测试,得到新研制传感器的探测可燃气体甲烷、丙烷、丁烷爆炸下限(Lower Explosive Limit, LEL)分别为0.1%LEL、0.8%LEL、0.9%LEL,而助燃剂氧气测量下限的体积分数为3%,均符合油气领域的最低检测标准要求。
    结论 对传感器各类干扰影响因素进行了深入分析,进一步提升了油气管网多场景泄漏风险的防控与预警能力,可为打造“平安管道、绿色管道、发展管道、友谊管道”提供技术支撑。

     

    Abstract:
    Objective Traditional gas monitoring methods for oil and gas leakage fall short in meeting the growing demands for the safe operation and maintenance of smart pipeline networks, due to factors such as low detection sensitivity levels, short calibration intervals, frequent false alarms, limited ranges of detectable gases, susceptibility to environmental interference, and reliance on charged sensors. Consequently, there is an urgent need to develop monitoring sensors that are suitable for detecting oil and gas leakage in emerging complex scenarios.
    Methods Considering various confined space scenarios, including primary and secondary seals, pontoons, tunnels, underground spaces, and laboratories within the context of oil and gas pipeline storage and transportation, a new type of diffusion sensor probe was designed, which is suitable for field deployment. This probe features all-fiber coupling, intrinsic safety, and networking capabilities. It is specifically aimed at simultaneously monitoring multiple selected parameters, including combustible gases (methane, propane, and butane), combustion-supporting gas (oxygen), and temperature. By leveraging spectral analysis for complex systems and employing a design approach focused on background noise removal, traditional tunable diode laser absorption spectroscopy (TDLAS) technology was integrated with partial least squares (PLS) algorithm, non-negative least squares (NNLS) algorithm, and artificial intelligence models. Utilizing the following central absorption spectra—oxygen at −761.0 nm, methane at −1,653.0 nm, propane at −1,686.1 nm, and butane at −1,686.5 nm—a generic technique was proposed to address interference caused by absorption spectrum aliasing during the measurements of alkane gas molecules. Furthermore, a multi-component gas concentration measuring sensor was developed, suitable for detecting oil and gas leaks in various scenarios.
    Results The developed sensor system was implemented in the long-distance, safe, and stable real-time monitoring and analysis of multi-component gases and integrated temperature data. With the capability of monitoring multiple parameters at various points across a wide dynamic range, it effectively met gas monitoring requirements in diverse application scenarios. Experimental testing of the sensor demonstrated the lower explosive limits (LEL) for detecting combustible gases: 0.1% for methane, 0.8% for propane, and 0.9% for butane. Additionally, the minimum volume fraction of oxygen was recorded at 3%. These results fell within the minimum detection standard requirements established for the oil and gas industry.
    Conclusion This in-depth analysis of various factors related to sensor interference provides insights for enhancing fire risk prevention and warning capabilities in oil and gas pipeline networks across multiple scenarios. It supports the goal of making pipelines safe and green conduits of development and friendship.

     

/

返回文章
返回